8,500 YEARS OF LEAD
9 YEARS OF LEADED GASOLINE
BC: - 6500 BC. Lead discovered in Turkey.
- 3000 BC. First significant production of lead.
- 500 BC-300 AD. Roman lead smelting produces dangerous emissions.
- 100 BC. Greek physicians give clinical description of lead poisoning.
1800s: - 1854. Tetraethyl lead (TEL) discovered by German chemist.
- 1887. US medical authorities diagnose childhood lead poisoning.
1900s: - 1904. Child lead poisoning linked to lead-based paints.
- 1909. France, Belgium and Austria ban white-lead interior paint.
1910s: - 1914. Pediatric lead-paint poisoning death from eating crib paint is described.
- 1916. GM and United Motors buy Charles Kettering's DELCO, which experiments with preventing engine knock.
- 1918. Scientific American reports alcohol-gasoline blend can be used as motor fuel.
- 1918. Thomas Midgley patents benzene/gasoline blend as antiknock.
- 1919. Du Pont interests buy additional shares of GM.
- 1919. London General Omnibus Co. experiments prove ethanol is antiknock.
- 1919. Kettering gives Midgley two weeks to find antiknock.
1920s: - 1920. US Naval Committee approves alcohol-gasoline blend.
- 1920. Midgley patents alcohol and cracked (olefin) gasoline blend.
- 1920. Du Pont now owns more than 35 percent of GM. 1921. National Lead Company admits lead is a poison.
- 1921. Midgley demonstrates car powered by 30 percent alcohol-gasoline blend.
- 1921. Midgley discovers that tetraethyl lead (TEL) curbs engine knock.
- 1922. League of Nations bans white-lead interior paint; US declines to adopt.
- 1922. GM contracts Du Pont to supply TEL.
- 1922. Public Health Service (PHS) warns of dangers of lead production, leaded fuel.
- 1922. Scientists express concern to Midgley over TEL in gas.
- 1923. Midgley repairs to Miami to recover from lead poisoning.
- 1923. Leaded gasoline goes on sale in selected markets.
- 1923. GM Chemical Corporation established to produce TEL.
- 1923. First Du Pont TEL plant opens at Deepwater, NJ.
- 1923. First TEL-poisoning deaths occur at Deepwater plant.
- 1923. GM contracts toothless Bureau of Mines to test TEL.
- 1924. Two GM employees die of lead poisoning at TEL plant. Dr. Robert Kehoe hired to study hazards at plant. Begins career as lead's lead apologist.
- 1924. GM forms medical committee to examine lead threat.
- 1924. Standard Oil begins production of TEL at Bayway plant.
- 1924. GM and Standard Oil of NJ form Ethyl Gasoline Corp.
- 1924. GM medical committee delivers negative and highly cautionary report on TEL. Irénée du Pont "not disturbed."
- 1924. Five workers die of lead poisoning at Bayway plant.
- 1924. NY Board of Health bans sales of TEL-enhanced gasoline.
- 1924. Bureau of Mines study gives TEL clean bill of health.
- 1924. Standard Oil suspends sale of leaded gasoline in NJ.
- 1924. Officials of GM, Standard, Du Pont request Surgeon General hold public hearings.
- 1925. Forgetting ethanol, Midgley proclaims TEL is only viable antiknock.
- 1925. Yale's Yandell Henderson warns of danger from breathing lead dust in auto emissions.
- 1925. Du Pont opens second TEL plant.
- 1925. Ethyl withdraws its gasoline from market until Surgeon General's conference.
- 1925. SG's conference calls for expert committee to study TEL.
- 1926. Committee calls for regulating sales of Ethyl and for further study by PHS, funded by Congress (studies never funded).
- 1926. Signs in gas stations: "Ethyl is back."
- 1926. Du Pont reopens Deepwater TEL plant.
- 1926. GM President Sloan expresses concern about valve corrosion with Ethyl.
- 1927. GM quells rebellion of dealers against use of lead fuel.
- 1928. Lead Industries Association formed to combat "undesirable publicity."
- 1928. Surgeon General tells NYC there are "no good grounds" to ban TEL.
1930s: - 1930. Ethyl Export is founded in England to sell leaded gas overseas.
- 1932. British Medical Journal cites "slow, subtle insidious saturation of the system by infinitesimal doses of lead extending over long period of time."
- 1933. USDA, naval researchers find Ethyl and 20 percent ethanol blend equal in performance.
- 1934. Ethyl and I.G. Farben form Ethyl GmbH to make leaded airplane fuel.
- 1936. 90 percent of gasoline sold in US contains Ethyl.
- 1938. Ethyl Export becomes Associated Ethyl Company.
1940s:
- 1943. Report concludes eating lead paint chips causes physical and neurological disorders, behavior, learning and intelligence problems in children.
- 1948. US files antitrust suit against Du Pont to break up "largest single concentration of power in the United States." Main target is Du Pont's $560 million investment in GM.
1950s: - 1950. Dr. Arie Haagen-Smit identifies causes of smog in LA as interaction of hydrocarbons (cars largest source) and oxides of nitrogen.
- 1952. Justice Dept antitrust suit against Du Pont focuses on anticompetitve association between it, GM, Standard Oil and Ethyl.
- 1954. Octel begins TEL production in England.
- Mid-1950s. Auto makers pact stifles development of emissions-control devices.
- 1959. PHS approves Ethyl request to increase lead in gasoline. PHS regrets that SG committee's 1926 call for studies was not followed up.
1960s: - 1961. Ethyl and Associated Octel compete for overseas trade.
- 1962. Ethyl sold to Albemarle Paper Co. in $200 million leveraged buyout partly financed by sellers, GM and Standard Oil.
- 1965. Clair Patterson's study "Contaminated and Natural Lead Environments of Man" offers first hard proof that high lead levels in industrial nations are man-made and endemic.
- 1966. Senate Public Works Committee holds first hearings on air pollution.
- 1969. Auto makers settle suit by Justice Department for conspiracy to delay the development of pollution-control devices.
1970s: - 1970. Passage of Clean Air Act.
- 1970. To avert threatened legislation to restrict use of internal-combustion engine, GM agrees to add catalytic converters to meet Clean Air law. Active element of converters--platinum--is contaminated by leaded gas, presaging its demise.
- 1971. Lead-Based Paint Poisoning Prevention Act passed.
- 1972. EPA gives notice of proposed phaseout of lead in gasoline. In first use of Freedom of Information Act, Ethyl sues EPA.
- 1973. EPA promulgates lead phaseout in gasoline but delays setting standards. When standards are set, EPA sued by Ethyl.
- 1976. EPA standards upheld by US Court of Appeals, and Supreme Court refuses to hear appeal.
- 1978. Energy Tax Act creates ethanol tax incentive, expanding use of ethanol in US.
1980s:
- 1980. National Academy of Sciences calls leaded gasoline greatest source of atmospheric lead pollution.
- 1980. National Security Act of 1980 mandates all gasoline be blended with a minimum of 10 percent grain alcohol--"gasohol." Subsequently scuttled by Reagan Administration.
- 1980. Gasohol Competition Act passed by Congress to stop oil companies' discrimination against sales of gasohol at their pumps.
- 1980. Ethyl reports it has expanded its overseas business tenfold between 1964 and 1981; profits help fund diversification.
- 1981. Vice President George Bush's Task Force on Regulatory Relief proposes to relax or eliminate US leaded gas phaseout.
- 1982. Reagan Administration reverses opposition to lead phaseout.
- 1983. Between 1976 and 1980, EPA reports, amount of lead consumed in gasoline dropped 50 percent. Blood-lead levels dropped 37 percent. Benefits of phaseout exceed costs by $700 million.
- 1986. Primary phaseout of leaded gas in US completed.
1990s:
- 1992. Rio environmental summit calls for worldwide lead phaseout.
- 1994. Study shows that US blood-lead levels declined by 78 percent from 1978 to 1991.
- 1994. American Academy of Pediatrics study shows direct relationship between lead exposure and IQ deficits in children.
- 1996. World Bank calls for world phaseout of leaded gasoline.
2000s:
- 2000. European Union bans leaded gasoline.
Feature story: Getting the Lead Out
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